TUBE NEWS TN June 2018 | Page 23

Coating type Corrosion test duration, hr 2200 (3 months) 4400 (6 months) 8760 (1 year) Average corrosion rate, g/m2 hr Corrosion depth index, μm/yr Average corrosion rate, g/m2 hr Corrosion depth index, μm/yr Average corrosion rate, g/m2 hr Corrosion depth index, μm/yr 33.4 0.0173 21.1 0.0060 7.3 4.8 0.0024 2.9 0.0022 2.6 193.4 0.1321 146.9 0.0923 102.6 Hot-dip zinc 0.0274 coating (in a zinc melt) Diffusion zinc coating (in powder mixtures) 0.0039 Non-coated steel 0.1740 nipples (for comparison) Table 3. Results of corrosion tests of zinc coatings in a moving medium of hot water supply systems Diffusion zinced lifting pipes were dipped for industrial tests in deep gaslift oil wells and monitored during the test period. The test program included periodic lifting of the pipe columns for inspection and taking samples of pipes and couplings for examining state of the diffusion zinc coating, its thickness change (Table 4) and physico-mechanical characteristics of pipes and couplings. Inspection of the pipes showed that the surface of the diffusion-zinced lifting pipes did not have any corrosion damage or any damage to the coating layer. After taking samples for laboratory testing, the column of diffusion zinced lifting pipes was again dipped into the well to continue industrial tests. Thus, even when the lifting pipes were operated for 65 months in complicated oil and gas production conditions, reduction in the coating thickness was 15% less on the external surface and up to 50% less on the inner surface subjected to crrosion-erosion wear. Time from the test start, mos. 0 Coating 39-56 thickness on the outside surface, μm Coating 35-65 thickness on the inside surface, μm 21 mos. 40 mos. 65 mos. 34-48 34-47 35-40 25-50 15-35 15-30 Table 4. Data of metallographic studies of thickness change of diffusion zinc coating on lifting pipes during long-term industrial tests in an oil well. Further studies have established that during operation of diffusion zinced products in corrosive media, dense layers of corrosion products were formed on their surface. They possessed protective properties and protected the underlying coating layers from destruction (self-protection effect). » TUBE NEWS June 2018 23