StomatologyEduJ 5(1) SEJ_5_2_site | Page 24

BEAM PROFILE CHARACTERIZATION OF A DENTAL LIGHT CURING UNIT USING A SPECTROMETER-BASED METHOD Figure 5. Beam profile images using the camera-based beam profiler method for the blue and violet wavelength ranges at 1, 1.5, 2.5 mm distance from the light tip. Table 1. Slope of the decrease in irradiance in mW/cm 2 /mm with respect to the vertical distance of the geometric center of LCU and the NORTH, SOUTH, WEST and EAST directions using the spectrometer-based method or the camera-based method. 1 mm 1.5 mm Spectrometer- based method Camera-based method Spectrometer- based method Camera-based method Spectrometer- based method Camera-based method NORTH -232 -231 -195 -183 -169 -171 SOUTH -244 -180 -201 -176 -142 -141 WEST -173 -167 -171 -148 -100 -142 EAST -197 -156 -181 -146 -127 -132 light as shown in Fig. 3. In Figure 1 the position of the LEDs in the head of the light is clearly visible. Using the beam profiler and different filters the center LED was identified to emit light blue light (420 – 495 nm) with a peak emission at 450 nm with a high intensity (1579 mW/cm 2 ) and the four LEDs in the “corners” emitting violet light (380 – 420 nm) with a peak emission at 390 nm, confirming measurements on other LCUs [23,27]. Furthermore it was noticed that the irradiance from the violet LEDs was quite low (102 mW/cm 2 ) and localized to the corners only. This discrepancy in the blue and violet light emission could be attributed to the type of the LED chip used to build the LCU. Despite the fact that the majority of LED chips are violet, they appear to be a dual in-line package (DIP) LED type, which have much lower energy efficiency than the blue light chip that appears to be a chip on-board (COB) LED type, which is considered a high-powered LED chip and the most recent development in LED LCUs. But, the fact is that “alternative” photoinitiators such as TPO or Ivocerin that have been used in commercial formulations are known as high reactive photoinitiators because they usually have higher molar extinction coefficient than CQ. This means that these photoinitiators absorb light 88 2 mm more efficiently than CQ at their peak wavelength absorptions. Moreover, these photoinitiators form more free radicals (two or more) that have higher nucleophilicity and electron resonance than the one amino radical formed by the CQ-amine electron donor/ hydrogen abstraction reaction. Thus, despite the less amount of violet light being emitted by broad spectrum LCUs, the initiation of the polymerization is effective enough to keep the physical and chemical properties of RBC containing “alternative” photoinitiators. However, it is important to bear in mind that broad spectrum LCUs typically have a ratio of 66 to 86 % of blue light emission and 14 to 34 % of violet light emission from the total spectral radiant power emitted [33] by the LCU. However, the LCU used in this study had 94% of blue light emission and 6% of violet light emission and further investigation should be performed to check if the LCU used in this study would efficiently cure RBC containing “alternative” photoinitiators. Therefore, it was decided that the impact on polymerization of these violet emitting LEDs was low and for further considerations we concentrated on the blue light. In the present study, the LCU was laterally moved in a controlled way in the x- and y-direction of a coordinated Stoma Edu J. 2018;5(2): 84-91 http://www.stomaeduj.com